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Abstract We present Atacama Large Millimeter/submillimeter Array observations with a 800 au resolution and radiative-transfer modeling of the inner part (r≈ 6000 au) of the ionized accretion flow around a compact star cluster in formation at the center of the luminous ultracompact Hiiregion G10.6-0.4. We modeled the flow with an ionized Keplerian disk with and without radial motions in its outer part, or with an external Ulrich envelope. The Markov Chain Monte Carlo fits to the data give total stellar massesM_⋆from 120 to 200M_⊙, with much smaller ionized-gas massesM_ion-gas= 0.2–0.25M_⊙. The stellar mass is distributed within the gravitational radiusR_g≈ 1000 to 1500 au, where the ionized gas is bound. The viewing inclination angle from the face-on orientation isi= 49°–56°. Radial motions at radiir>R_gconverge tov_r,0≈ 8.7 km s⁻¹, or about the speed of sound of ionized gas, indicating that this gas is marginally unbound at most. From additional constraints on the ionizing-photon rate and far-IR luminosity of the region, we conclude that the stellar cluster consists of a few massive stars withM_star= 32–60M_⊙, or one star in this range of masses accompanied by a population of lower-mass stars. Any active accretion of ionized gas onto the massive (proto)stars is residual. The inferred cluster density is very large, comparable to that reported at similar scales in the Galactic center. Stellar interactions are likely to occur within the next million years. 

Reactions of {(C 6 F 5 )Pt[S(CH 2 CH 2 -) 2 ](μ-Cl)} 2 and R 3 P yield the bis(phosphine) species trans -(C 6 F 5 )(R 3 P) 2 PtCl [R = Et ( Pt'Cl ), Ph, ( p -CF 3 C 6 H 4 ) 3 P; 88-81 %]. Additions of Pt'Cl and H(C≡C) n H ( n = 1, 2; HNEt 2 , 20 mol % CuI) give Pt'C 2 H (37 %, plus Pt'I , 16 %) and Pt'C 4 H (88 %). Homocoupling of Pt'C 4 H under Hay conditions (O 2 , CuCl, TMEDA, acetone) gives Pt'C 8 Pt' (85 %), but Pt'C 2 H affords only traces of Pt'C 4 Pt' . However, condensation of Pt'C 4 H and Pt'Cl (HNEt 2 , 20 mol % CuI) yields Pt'C 4 Pt' (97 %). Hay heterocouplings of Pt'C 4 H or trans -( p -tol)(Ph 3 P) 2 Pt(C≡C) 2 H ( Pt*C 4 H ) and excess HC≡CSiEt 3 give Pt'C 6 SiEt 3 (76 %) or Pt*C 6 SiEt 3 (89 %). The latter and wet n -Bu 4 N + F - react to yield labile Pt*C 6 H (60 %). Hay homocouplings of Pt*C 4 H and Pt*C 6 H give Pt*C 8 Pt* (64 %) and Pt*C 12 Pt* (64 %). Reaction of trans -(C 6 F 5 )( p -tol 3 P) 2 PtCl ( PtCl ) and HC≡CH (HNEt 2 , 20 mol % CuI) yields only traces of PtC 2 H . However, an analogous reaction with HC≡CSiMe 3 gives PtC 2 SiMe 3 (75 %), which upon treatment with silica yields PtC 2 H (77 %). An analogous coupling of trans -(C 6 F 5 )(Ph 3 P) 2 PtCl with H(C≡C) 2 H gives trans -(C 6 F 5 )(Ph 3 P) 2 Pt(C≡C) 2 H (34 %). Advantages and disadvantages of the various trans -(Ar)(R 3 P) 2 Pt end-groups are analyzed.